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You choose the solvent system and the reference electrode for the calculation.

The system will then calculate the reduction potential for this system by performing a thermodynamic loop calculation. First the gas phase equivalent (electron affinity) is performed and then two free energy of transfer calculations are performed (Henry's constants for gas/liq). The sum of these along with the reference electrode energy yields the E 1/2 in e.v.

Click here to watch a tutorial video.